This article will show you how to add users to a Volunteer Opportunity.
Instructions
Navigate to Catalog
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Search for and select the user Account
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Select the appropriate tab with the Volunteer Opportunity session

Select the session
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Click Add To Cart
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Click Checkout
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Read and confirm any applicable Waivers and Prompts (these will vary depending on the activity)
Review the Payment screen

If needed, Add a Payment option
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Select Complete Transaction
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You can now assign participants a volunteer role